MODELING OF ELECTROPHYSICAL TRANSFORMATIONS IN FIREPROOF COMPOSITIONS OF ETHYLENE-VINYL ACETATE COPOLIMER AND ALUMINUM OXIDE TRIHYDRATES
DOI:
https://doi.org/10.30857/1813-6796.2019.1.7Keywords:
fireproof compositions, ethylene-vinyl acetate copolymer, modifier, fire retardant, electrophysical propertiesAbstract
To determine the rational composition of fireproof polymer compositions with improved electrophysical characteristics, which composed of an ethylene-vinyl acetate copolymer and aluminum trihydroxide based on the results of studies of the dependence of electrical strength, specific volume electrical resistance, dielectric loss tangent and physical permittivity of the ingredients and the amount and modifier properties. Ethylene-vinyl acetate copolymer and aluminum trihydroxide polymer compositions which had different content of organosilane as a modifier were manufactured on the compounding line of X-Compound, Switzerland. To assess the insulating properties of the material used methods for measuring the electrical strength, specific volume electrical resistance, dielectric constant and tangent of dielectric loss. Findings. The dependences of changes in the electrophysical properties of fireproof plymer
compositions depending on the rheological properties of the polymer matrix and the physicochemical properties of aluminum oxide trihydrates are revealed. The effect of nano-modifiers based on organosilanes on the properties of the compositions was investigated. The phenomenon of a synergistic effect with the use
of modified mixtures was found. Originality.The effect of modifiers on the electrophysical properties of fireproof polymer compositions and the synergistic effect of their action is established. It is shown that the addition of 60% of the mass. aluminum oxide trihydrate 2 in a composition based on ethylene-vinyl acetate copolymers with the content of aminosilane 1 in the amount of 1.5% by weight. provides improved electrical insulation properties of the material. Practical value. The practical features of modeling the electrophysical properties of fireproof polymer compositions, which consist in the choice of a rational composition to achieve the specified own.
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Published
2019-06-05
Issue
Section
Chemical, Biological & Pharmaceutical Technologies